Search results for "chemistry [Arsenates]"
showing 10 items of 2372 documents
Pathways and fate of REE in the shallow hydrothermal aquifer of Vulcano island (Italy)
2019
Abstract We investigated the geochemical behaviour of major and Rare Earth Elements (REE), together with oxygen and deuterium isotopic composition in the aquifer of Vulcano, the southernmost island of the Aeolian archipelago (Italy). Studied wells, located at different distances from the crater, are characterised by different contributions of the rising volcanic fluids. In particular, those located in the proximity of La Fossa crater are affected by a strong interaction with volcanic-hydrothermal fluids and show REE behaviour similar to that of fresh rocks, suggesting a congruent dissolution of the solid matrix. Samples from the other wells, located in an area where the volcanic deposits ar…
Porites corals from Crete (Greece) open a window into Late Miocene (10Ma) seasonal and interannual climate variability
2006
Variations in the biotic composition of marine shallow water carbonates document global climatic changes. However, a discontinuous stratigraphic record and uncertainties regarding the ages limit the significance of shallow water carbonates as palaeoclimatic archives on geological time-scales. Notwithstanding these deficits, the environmental information stored in the skeleton of reef biota is a unique source of information that resolves seasonal to interannual climate variability in geological time. Application of the method to corals from carbonate rocks is usually restricted to the past 130,000yr, because the aragonite skeleton undergoes rapid diagenetic alteration. Consequently, reconstr…
The complexities of zircon crystllazition and overprinting during metamorphism and anatexis: An example from the late Archean TTG terrane of western …
2017
Abstract There are different viewpoints on metamorphic and anatectic zircons recording ages of 2.45–2.48 Ga or even younger in some areas of the North China Craton where both late Neoarchean and late Paleoproterozoic tectono-thermal events are well developed. These are: 1) partial resetting of the U-Pb isotopic system in the late Neoarchean zircons, 2) metamorphism lasting from the late Neoarchean to the earliest Paleoproterozoic, and 3) earliest Paleoproterozoic metamorphism as separate different event. Western Shandong Province is an area where the late Neoarchean tectono-thermal event is widely developed but the late Paleoproterozoic event has not been identified. This provides an opport…
Xenoliths from the sub-volcanic lithosphere of Mt Taranaki, New Zealand
2010
Abstract Mount Taranaki is located 140 km west of the Taupo Volcanic Zone and represents the most westerly expression of subduction-related volcanism on the North Island of New Zealand. Taranaki is a predominantly high-K arc volcano but compositions range from basaltic andesite to andesite with minor dacite and basalt. The sub-volcanic basement under Taranaki is thought to comprise calc–alkaline plutonic and metamorphic rocks of the Median Batholith, overlain by a sequence of Cretaceous and Tertiary sediments. Taranaki lavas contain abundant xenoliths that represent samples of the upper to lower crust beneath the volcano. The xenolith suite has been initially organised into six groups based…
Mercury gas emissions from La Soufrière Volcano, Guadeloupe Island (Lesser Antilles)
2009
Abstract Quantifying mercury (Hg) emissions from active volcanoes is of particular interest for better constraining the global cycle and environmental impact of this highly toxic element. Here we report on the abundance of total gaseous (TGM = Hg 0 (g) + Hg II (g) ) and particulate (Hg (p) ) mercury in the summit gas emissions of La Soufriere andesitic volcano (Guadeloupe island, Lesser Antilles), where enhanced degassing of mixed hydrothermal-magmatic volatiles has been occurring since 1992 from the Southern summit crater. We demonstrate that Hg in volcanic plume occurs predominantly as gaseous mercury, with a mean TGM/Hg (p) mass ratio of ~ 63. Combining the mean TGM/H 2 S mass ratio of …
Influences of surface processes on fold growth during 3-D detachment folding
2014
In order to understand the interactions between surface processes and multilayer folding systems, we here present fully coupled three-dimensional numerical simulations. The mechanical model represents a sedimentary cover with internal weak layers, detached over a much weaker basal layer representing salt or evaporites. Applying compression in one direction results in a series of three-dimensional buckle folds, of which the topographic expression consists of anticlines and synclines. This topography is modified through time by mass redistribution, which is achieved by a combination of fluvial and hillslope erosion, as well as deposition, and which can in return influence the subsequent defor…
Moroccan speleothem and tree ring records suggest a variable positive state of the North Atlantic Oscillation during the Medieval Warm Period
2013
We present a magnesium (Mg) and strontium (Sr) record from an aragonitic speleothem (Grotte de Piste, Morocco, 34°N; 04°W) providing a reconstruction of effective rainfall from 619 to 1962 AD. The corresponding drip site was monitored over 2 yr for drip water Mg/Ca and Sr/Ca ratios. Results show evidence for prior aragonite precipitation, which can explain negative correlations between speleothem Mg and Sr concentrations. The data shown here have important climate implications concerning the evolution of the North Atlantic Oscillation (NAO). A comparison of the stalagmite data from Grotte de Piste with an updated tree ring based drought reconstruction from Morocco and other NAO related pro…
Archean-Paleoproterozoic crustal evolution of the Ordos Block in the North China Craton: Constraints from zircon U–Pb geochronology and Hf isotopes f…
2015
Abstract The Ordos Block has been considered as an Archean micro-block in North China Craton. However, its formation and evolution are poorly understood for a long time due to lack of available basement rocks. Our LA-ICPMS and SIMS zircon U–Pb dating of gneissic granitoids from the Ordos Block basement identified two distinct periods of granitic magmatism at ∼2.5 Ma and 2.2–2.0 Ga, and two phases of metamorphisms at ∼1.95 Ga and ∼1.85 Ga, respectively. Of which most zircons of ∼2.5 Ga granitoids show positive ɛ Hf ( t ) values ranging from +0.1 to +4.1 with a peak T DM of ∼2.7 Ga. Minor zircons have negative ɛ Hf ( t ) values from −3.8 to −0.02 and T Hf C of 2.8–3.1 Ga. Moreover, the 3.40 G…
Archaean to Neoproterozoic magmatic events in the Kaoko belt of NW Namibia and their geodynamic significance
1998
Abstract Age relationships in the N–S trending Neoproterozoic (Pan-African) Kaoko belt of northwestern Namibia are still poorly constrained. U–Pb and Pb–Pb zircon age determinations by single grain evaporation, conventional multigrain fraction analyses and ion microprobe (SHRIMP) from a profile along the E–W Hoanib River reveal various episodes of zircon growth, ranging from late Archaean to late Neoproterozoic. From the eastern part of the profile we report crystallization ages of gneiss protoliths from 2645 to 2585 Ma, the oldest ages so far found in Namibia. Sm–Nd isotope data suggest the involvement of still older crustal material in the generation of these gneisses. A thermal event at …
Zircon geochronology and metamorphic evolution of mafic dykes in the Hengshan Complex of northern China: Evidence for late Palaeoproterozoic extensio…
2006
Abstract Magmatic and metamorphic zircons have been dated from ductilely deformed gabbroic dykes defining a dyke swarm and signifying crustal extension in the northern part of the Hengshan Complex of the North China Craton. These dykes now occur as boudins and deformed sheets within migmatitic tonalitic, trondhjemitic, granodioritic and granitic gneisses and are conspicuous due to relics of high-pressure granulite or even former eclogite facies garnet + pyroxene-bearing assemblages. SHRIMP ages for magmatic zircons from two dykes reflect the time of dyke emplacement at ∼1915 Ma, whereas metamorphic zircons dated by both SHRIMP and evaporation techniques are consistently in the range 1848–18…